Tuesday, May 7, 2013

THE DEATH OF JAMES ARTHUR?

James Arthur (aka James Dugovic or James Dugovic Arthur) was an infamous lay ethnomycologist and author of Mushrooms and Mankind, a book I find interesting for reasons entirely separate from Arthur's original intention. Mushrooms and Mankind serves as a timeless testament to the power of pareidolia in the wishful male psychomycophile, there are few other published works that indulge such freewheeling speculation in an effort to prove the central role of mushrooms in human history. 

But even more interesting than Mushrooms and Mankind is the issue of James Arthur's pedophilia. I am a proficient Google searcher (an exceedingly rare skill) and so I've read discussions of the topic posted on the Shroomery and various other mushroom and psychedelic interest forums. I have also seen his mugshot and the formal listing of his crimes including: 

*Lewd or lascivious acts with a child under 14 years
*Assault to commit mayhem, rape, etc.
*Continuous sexual abuse of a child
*Oral copulation with a person under 14 years
*Oral copulation with force

I am posting this because I am looking for detailed information on James Arthur's sex crimes, either in the form of a police incident report, an arrest affidavit, a case disposition report, or similar. There is a wealth of anecdotal and second-hand information but I am looking for verifiable first-hand reports and formal documentation.

Tuesday, March 26, 2013

5-Br-DMT: SYNTHESIS AND EFFECTS

Please enjoy a new article on marine psychedelics that I wrote with Jason Wallach. It details a synthetic route to 5-Br-DMT as well as TiHKAL-style analysis of the subjective effects of the compound in human experimenters.



Wednesday, February 13, 2013

SCREENING AT BRANDEIS UNIVERSITY

Dear Massachusettsians, tomorrow I will be screening select episodes of Pharmacopeia (as well as some new unaired footage) at Brandeis University. The screening will be followed by a Q&A and is free of charge. I hope to see you there.


Wednesday, December 5, 2012

FREDERIK HEINZ BARTH

I am looking to contact Frederik Heinz Barth, we had a written exchange in 2008 but I've since been unable to get messages to you. If you read this please send me an email as I would like to reconnect to ask a question about the synthesis of substituted 1,8-naphthyridines.

Saturday, November 24, 2012

MARKOVNIKOV DIBROMIDE

I am contemplating some hypothetical difficulties in the synthesis of 2,5-dibromohexane from 1,5-hexadiene. I am aware that this is a simple reaction that can be achieved in many ways but I would like to accomplish it in such a way that a messy separation is minimally necessary, be it via selective chemical extraction, column chromatography, or fractional distillation. The main unwanted side-products in this synthesis would be the mixed-Markovnikov product and the full anti-Markovnikov product. My first option is simple bromination with (aq) HBr and an appropriate phase transfer catalyst or a similar reaction involving hydrogen bromide gas. My second option is oxymercuration-demurcuration yielding hexane-2,5-diol which can then be subjected to a high yielding and selective bromination with PBr3. The third option is acid catalyzed hydration to the diol with H2SO4 and water followed by bromination with PBr3.

I would prefer not to use hydrogen bromide gas or mercuric acetate (which will require recycling of the metallic mercury liberated during demercuration) and so I lean toward acid catalyzed hydration. Would anyone with practical experience using the above methods enlighten me regarding their relative regioselectivity for the Markovnikov product? I believe it would be something like this: oxymercuration-demurcuration>acid catalyzed hydration>HBr addition.

Sunday, November 11, 2012